Hydride lithiation of spinels LiMn2O4 |
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| Authors: | G. A. Buzanov G. D. Nipan K. Yu. Zhizhin N. T. Kuznetsov |
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| Affiliation: | 1.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia |
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| Abstract: | ![]()
Undoped lithiation of stoichiometric spinel using lithium hydride LiH up to the composition Li2.25Mn2O4 was performed. A homogeneous material with a given Li: Mn ratio was obtained by mechanochemical activation with sequential annealing of a LiMn2O4–LiH mixture in a high-purity argon atmosphere and then in air or oxygen at 373–553 K. |
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