The influence of sub-Tg annealing on environmental stress cracking resistance of polycarbonate |
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| Institution: | 1. School of Materials Science and Engineering, Zhengzhou University, 100 Kexue Road, 450001, Zhengzhou, PR China;2. National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, 97 Wenhua Road, 450002, Zhengzhou, PR China;1. School of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, China;2. College of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong 643000, China;1. School of Mechanical Engineering, Guangdong Mechanical and Electrical College, Guangzhou 510515, China;2. National-certified Enterprise Technology Center, Kingfa Scientific and Technological Co. Ltd., Guangzhou 510663, China;3. College of Materials Science and Engineering, Key Laboratory of Polymer Processing Engineering of the Ministry of Education, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | To explore the effect of physical aging on environmental stress cracking (ESC) behavior of polycarbonate (PC), sub-Tg annealing was utilized as a method for accelerated aging. Injection molded samples were annealed at 130 °C for different time varying up to 96 h. A three point bending apparatus was used to evaluate critical stress for crazing and to record the variation of stress with immersion time at constant strain. The ESC results indicated that the critical stress for crazing initiation of PC in ethanol is increased by sub-Tg annealing. However, the resistance of annealed PC to ESC with immersion time during the stress relaxation test depends on the level of initial stress. When a relatively low initial stress was used, a short time (24 h) of sub-Tg annealing reduced the stress relaxation rate and decreased the number of cracks on the surface of PC. However, under higher initial stress, the stress relaxation rate of PC had a slight change only when the annealing time was prolonged about threefold (72 h). This can be explained by the formation of cohesional entanglement sites during the sub-Tg annealing process, which was demonstrated by the thermal and dynamic mechanical tests. |
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| Keywords: | Environmental stress cracking Polycarbonate Stress relaxation Cohesional entanglement |
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