One-step conversion to tertiary amines: InBr<sub>3</sub>/Et<sub>3</sub>SiH-mediated reductive deoxygenation of tertiary amides期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

One-step conversion to tertiary amines: InBr₃/Et₃SiH-mediated reductive deoxygenation of tertiary amides

Authors:	Norio Sakai Kohji Fujii Takeo Konakahara

Affiliation:	Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba 278-8510, Japan

Abstract:	We have developed a simple and practical procedure for a direct reductive conversion from a variety of tertiary amides to the corresponding tertiary amines using an InBr₃/Et₃SiH reducing system. This reducing system can be applied to the reduction of a secondary amide and provides a more efficient alternative to conventional methods that use aluminum and boron hydrides.

Keywords:	Reduction Amide Amine Indium Silane
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