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A new route to alkenylcyclobutenes
Authors:Shigeki Oishi
Affiliation:Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan
Abstract:Reaction of titanium cyclobutylidene complexes, prepared by the desulfurizative titanation of 1,1-bis(phenylthio)cyclobutanes with Cp2Ti[P(OEt)3]2, with alkynes gave 1-(alk-1-enyl)cyclobutenes.
Keywords:Alkenylcyclobutenes   Titanocene(II)   Alkynes   Carbene complexes
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