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The reaction of cis dioxobis(2,4 pentanedionato)molybdenum (VI) and 2,2′ pyridylbenzoxazole (L), a novel route to β[Mo8O26] |
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| Authors: | Brian Piggott Swee Fatt Wong |
| Institution: | Inorganic Chemistry Research Laboratory, Chemistry Department, The Hatfield Polytechnic, Hatfield, Herts AL10 9AB, U.K. Department of Chemistry, Queen Mary College, University of London, Mile End Road, London E1 4NS, U.K. |
| Abstract: | MoO2(C5H7O2)2, where C5H7O2 is 2,4-pentanedione (acac), reacts with 2-2′ pyridylbenzoxazole in acetone to give a product with stoichiometry, Mo3C24H16N6O12. This product dissolves readily in dimethylformamide to give a brown solution which on standing for several weeks yielded crystals. An X-ray structure determination showed these crystals to contain uncoordinated 2-2′pyridylbenzoxazole and (CH3)2NH2]4+Mo8O26]4?. |
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