Soft-lithographic approach to functionalization and nanopatterning oxide-free silicon |
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Authors: | Shestopalov Alexander A Morris Carleen J Vogen Briana N Hoertz Amanda Clark Robert L Toone Eric J |
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Institution: | Department of Chemistry, Duke University, Durham, North Carolina 27708, United States. |
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Abstract: | We report a simple, reliable high-throughput method for patterning passivated silicon with reactive organic monolayers and demonstrate selective functionalization of the patterned substrates with both small molecules and proteins. The approach completely protects silicon from chemical oxidation, provides precise control over the shape and size of the patterned features in the 100 nm domain, and gives rapid, ready access to chemically discriminated patterns that can be further functionalized with both organic and biological molecules. |
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