| Solid State Synthesis and Structural Characterizationof Binuclear Cu( I)-Sb Ph_3 Co m plex 〔 Cu( Sb Ph_3)_2 I〕 |
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| 作者姓名： | ZHANG Qian Feng\ ZENG Dong Xiang\ XIN Xin Quan\ * |
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| 作者单位： | ZHANG Qian Feng\ ZENG Dong Xiang\ XIN Xin Quan\ * ( State Key Laboratory of Coordination Chemistry，Coordination Chemistry Institute，Nanjing University，Nanjing 210093 |
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| 摘 要： | １ ＩＮＴＲＯＤＵＣＴＩＯＮＣｕ（Ｉ）ｃｏｍｐｌｅｘｅｓｗｉｔｈｐｈｏｓｐｈｉｎｅａｎｄａｒｓｉｎｅｌｉｇａｎｄｓａｒｅｗｅｌｌｋｎｏｗｎ〔１〕．ＦｏｒＣｕｐｈｏｓｐｈｉｎｅｃｏｍｐｌｅｘｅｓ，ｔｈｅＣｕ∶ｌｉｇａｎｄｒａｔｉｏｖａｒｉｅｓｆｒｏｍ１∶１ｔｏ１∶４ａｎｄｃｏｏｒｄｉｎａｔｉｏｎｇｅｏｍｅｔｒｙｏｆＣｕ（Ｉ）ｒａｎｇｅｓｆｒｏｍｌｉｎｅａｒｔｏｔｒｉｇｏｎａｌ，ｔｈｅｎｔｏｔｅｔｒａｈｅｄｒａｌｅｘｔｒｅｍｅｓ；ｆｏｒｅｘａｍｐｌｅ，ｔｈｅ１∶２ａｄｄｕｃｔｓＣｕ（ＰＰｈ３）…
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Solid State Synthesis and Structural Characterization of Binuclear Cu(I) SbPh 3 Complex 〔Cu(SbPh 3) 2I〕 2 |
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| ZHANG Qian,Feng\ ZENG Dong,Xiang\ XIN Xin,Quan\ *.Solid State Synthesis and Structural Characterization of Binuclear Cu(I) SbPh 3 Complex 〔Cu(SbPh 3) 2I〕 2[J].Chinese Journal of Structural Chemistry,1999(5). |
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| Authors: | ZHANG Qian Feng\ ZENG Dong Xiang\ XIN Xin Quan\ |
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| Institution: | ZHANG Qian Feng\ ZENG Dong Xiang\ XIN Xin Quan\ * |
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| Abstract: | Dimeric complex 〔Cu(SbPh 3) 2I〕 2 has been synthesized by a solid state reaction at a low heating temperature and its crystal structure has been analyzed by X ray crystallography. The crystal is monoclinic, space group P2 1/a (#14), a = 20 436(5), b=14.125(3), c=24.683(3) , β=110.67(1)°, Z=4, V =6666(2) 3; C 72 H 60 Sb 4I 2Cu 2, M r = 1792, D c = 1.787 g·cm -3 , μ (Mo Kα ) = 31.88 cm -1 , F(000)=3440, R= 0.038 and R w= 0.043 for 5632 observed reflections ( I≥3.0σ(I) ) and 361 refined parameters. The result reveals the copper and the bridging iodide atoms form an approximately planar rhomboid array. Effects of the bulkiness of the ligands upon the structures of the analogous complexes are discussed. |
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| Keywords: | solid state synthesis crystal structure Cu(I) SbPh 3 complex IR spectrum |
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