Catalyst-free Vicinal bromoazidation of olefins using TMSN3 and NBS |
| |
| Authors: | Indranirekha Saikia Prodeep Phukan |
| |
| Institution: | Department of Chemistry, Gauhati University, Guwahati, 781014 Assam, India |
| |
| Abstract: | A rapid and efficient method has been developed for the synthesis of vicinal bromoazide directly from olefin using N-bromosuccinimide (NBS) and trimethylsilyl azide (TMSN3) as the bromine and azide sources, respectively, without any catalyst in acetonitrile as solvent. The rate of reaction is remarkably fast in acetonitrile without catalyst to produce bromoazides in high yield. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
