| 一维链状高价锰配合物[Mn_2(C_7H_4O_3)_4(CH_3OH)_2]·4H_2O_2CH_3OH的合成与结构 |
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| 引用本文： | 李珺,张逢星,吴爱芝,史启祯,李一志,王流芳.一维链状高价锰配合物[Mn_2(C_7H_4O_3)_4(CH_3OH)_2]·4H_2O_2CH_3OH的合成与结构[J].结构化学,2003,22(1):93-96. |
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| 作者姓名： | 李珺 张逢星 吴爱芝 史启祯 李一志 王流芳 |
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| 作者单位： | 1. 西北大学化学系,陕西省物理无机化学重点实验室,西安,710069
2. 兰州大学化学与化工学院,兰州,730000 |
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| 基金项目： | 国家自然科学基金(20271041)，陕西省自然科学基金 |
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| 摘 要： | 合成了一维链状高价锰配合物Mn2(C7H4O3)4(CH3OH)2]4H2O2CH3OH,并对其进行了IR、X-射线衍射、UV-Vis和TG-DSC等表征。单晶衍射结果表明,该配合物晶体属三斜晶型,空间群P?晶胞参数a=7.653(5),b=10.486(7),c=12.943(8),=103.24(1),?=104.55(1),?=110.11(1),V=885.4(9)3,Z=1。UV-Vis光谱在547nm有一个吸收峰,相应于Mn(Ⅳ)的d-d电子跃迁光谱。
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| 关 键 词： | 一维链状Mn(Ⅳ)配合物 晶体结构 合成 |
Synthesis and Crystal Structure of One Dimensional Chain Manganese Complex [Mn2(C7H4O3)4(CH3OH)2]·4H2O·2CH3OH |
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| LI Juna,ZHANG Feng-Xinga,WU Ai-Zhia SHI Qi-Zhena,LI Yi-Zhib,WANG Liu-Fangb a.Synthesis and Crystal Structure of One Dimensional Chain Manganese Complex [Mn2(C7H4O3)4(CH3OH)2]·4H2O·2CH3OH[J].Chinese Journal of Structural Chemistry,2003,22(1):93-96. |
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| Authors: | LI Juna ZHANG Feng-Xinga WU Ai-Zhia SHI Qi-Zhena LI Yi-Zhib WANG Liu-Fangb a |
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| Abstract: | The one dimensional chain manganese complex Mn2(C7H4O3)4(CH3OH)2]4H2O2CH3OH has been synthesized, and it was characterized by IR, X-ray diffraction and UV-Vis. X-ray diffraction result shows that the crystal belongs to triclinic, space group P with a = 7.653(5), b = 10.486(7), c = 12.943(8) ,?= 103.24(1), ?= 104.55(1), ?= 110.11(1)? V = 885.4(9) 3 and Z = 1. UV-Vis spectrum result indicates there exists a peak at 547 nm, corresponding to the electron transition of d-d. |
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| Keywords: | one dimensional chain manganese (Ⅳ) complex crystal structure synthesis |
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