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| Synthesis and Crystal Structure of Ni_3(admt)_6(NCS)_6·C_2H_5OH·2H_2O | |
| 作者姓名： | 刘家成 宋友 庄金钟 游效曾 黄小荥 HUANG Zi-Xiang |
| 作者单位： | LIU Jia Cheng SONG You ZHUANG Jin Zhong * YOU Xiao Zeng (Coordination Chemistry Institute，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 210093 |
| 基金项目： | supported by the Foundation of State Key Laboratory of Structural Chemistry，Fuj中国科学院基金 |
| 摘 要： | 1 INTRODUCTIONCoordination compounds with 1 ,2 ,4 triazole as a ligand have interesting fea tures,notonly because ofthe very interesting magnetic propertiesofthese complex es,but also because ofrich modes ofcoordination〔1〕.Particularly,the coordinationbehavioroftriazoletowardsa numberoftransition metalthiocyanatesshowsremark abledifferences〔2 - 6〕.On unsubstitution at N4 ,thetriazole ring hasmonodentate,1 ,2 and 2 ,4 bridging forms.These three modes were all observed in the Ni( II)… |
| 关 键 词： | trinickel (Ⅱ) complex 4-amino-3 5-dimethyl-1 2 4-triazole thiocyanate crystal structure |
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