Ionic transformations in extremely nonpolar fluorous media: phase transfer catalysis of halide substitution reactions |
| |
| Authors: | Consorti Crestina S Jurisch Markus Gladysz John A |
| |
| Affiliation: | Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universit?t Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany. |
| |
| Abstract: | ![]()
Fluorous solutions of alkyl halides Rf8(CH2)mX (m = 2, 3; X = Cl, Br, I) are inert toward solid or aqueous NaCl, NaBr, and KI, but halide substitution occurs in the presence of fluorous phosphonium salts (10 mol %, 76-100 degrees C). |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
