| PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)_3~(2+) COMPLEXES |
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| 作者姓名： | 后晓淮 金子正夫 山田瑛 |
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| 作者单位： | Institute of Chemistry，Academia Sinica，Beijing，The Institute of Physical and Chemical Research，Wako-shi，351，Japan，The Institute of Physical and Chemical Research，Wako-shi，351，Japan |
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| 摘 要： | Polymeric pendant Ru(bpy)_3~(2+) complexes were prepared from homopolymer and copolymers of 4-methyl-4'-vinyl-2,2'-bipyridine (Vbpy). Vbpy was prepared from 4-methylpyridine. The comonomers were styrene (St), acrylic acid (AA), N-vinylpyrrolidone (Pyr), 4-vinylpyridine (Vpy), methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA), acrylonitrile (AN) and N-ethyl-4-vinylpyridium bromide (EQ-Vpy). The fraction of the pendant Ru(bpy)_3~(2+) repeating unit in the polymeric complex was 0.022 to 0.052. Absorption maximum, molar extinction coefficient, emission maximum and relative emission intensity of the polymeric complexes were studied.
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| 收稿时间： | 1984-02-24 |
PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)32+ COMPLEXES* |
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| HOU Xiaohuai,Masao Kaneko,Akira Yamada.PREPARATION AND PROPERTY OF POLYMERIC PENDANT Ru(bpy)_3~(2+) COMPLEXES[J].Chinese Journal of Polymer Science,1984,0(2):151-158. |
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| Authors: | HOU Xiaohuai Masao Kaneko Akira Yamada |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing; The Institute of Physical and Chemical Research; Wako-shi; 351; Japan |
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| Abstract: | Polymeric pendant Ru(bpy)32+ complexes were prepared from homopolymer and copolymers of 4-methyl-4'-vinyl-2,2'-bipyridine (Vbpy). Vbpy was prepared from 4-methylpyridine. The comonomers were styrene (St), acrylic acid (AA), N-vinylpyrrolidone (Pyr), 4-vinylpyridine (Vpy), methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA), acrylonitrile (AN) and N-ethyl-4-vinylpyridium bromide (EQ-Vpy). The fraction of the pendant Ru(bpy)32+ repeating unit in the polymeric complex was 0.022 to 0.052. Absorption maximum,molar extinction coefficient,emission maximum and relative emission intensity of the polymeric complexes were studied. |
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