Synthesis and Characterisation of a Thiocarbonyl containing Osmium Cluster |
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| Authors: | Peter V. Broadhurst Brian F.G. Johnson Jack Lewis A.Guy Orpen Paul R. Raithby John R. Thornback |
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| Affiliation: | University Chemical Laboratory, Lensfield Road, Cambridge, CB2 1EW England |
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| Abstract: | Reaction of CS2 with H2Os3(CO)8(MeCN)S in cyclohexane yields a product H2Os3(CO)7(CS)S2. this has been characterised by NMR and mass spectroscopy, and by X-ray analysis, and has been shown to contain a terminal thiocarbonyl ligand. |
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