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Ferrocenyltrithiocarbonates : I. Direct access from α-ferrocenylcarbinols by a SNi mechanism. Absolute x-ray structure determination of (R)-ferrocenylmethylmethane S-methyl-trithiocarbonate |
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| Authors: | Henri Patin Gerard Mignani Christian Mahe Jean-Yves Le Marouille Alain Benoit Daniel Grandjean |
| Institution: | Laboratoire de Chimie des Organométalliques, E.R.A. C.N.R.S., No. 477, Université de Rennes, Campus de Beaulieu, 35042 Rennes Cedex France;Laboratoire de Cristallochimie, L.A. C.N.R.S., No. 254, Université de Rennes, Campus de Beaulieu, 35042 Rennes Cedex France |
| Abstract: | 103Rh Chemical shifts of a variety of mono- and di-nuclear rhodium carbonyl complexes are reported together with the modifications to the probe and decoupler unit of a JEOL PS-100 PFT spectrometer which enable these 103Rh-decoupled 13C NMR measurements to be made. These data are discussed in conjunction with 13C NMR data on other rhodium carbonyls. |
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