Synthese und struktur von dicyclopentadienyl(trimethylsilyl)titanchlorid |
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| Authors: | Lutz Rösch Gerald Altnau Wolfgang Erb Joachim Pickardt Norbert Bruncks |
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| Institution: | Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, D-1000 Berlin 12, Strasse des 17, Juni 135 Deutschland |
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| Abstract: | Dicyclopentadienyl(trimethylsilyl)titanium chloride, a stable trimethylsilyltitanium compound, is synthesized by reaction of dicyclopentadienyltitanium dichloride and tris(trimethylsilyl)aluminium, coordinated with diethyl ether, or lithium tetarakis(trimethylsilyl)aluminate. The IR and NMR spectra are reported. The crystal structure of the title compound has been determined. It shows a distorted tetrahedral surrounding of the titanium atom; the Ti–Si distance is 267 pm. |
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| Keywords: | To whom correspondence may be addressed |
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