Darstellung und strukturuntersuchungen von dimethylmetallacet- und acetimidohydrazinderivaten des galliums und indiums |
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Authors: | F. Gerstner H.-D. Hausen J. Weidlein |
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Affiliation: | Institut für Anorganische Chemie der Universität Stuttgart, D-7000 Stuttgart-80, Pfaffenwaldring 55 Deutschland |
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Abstract: | Trimethylgallium and trimethylindium react with N′,N dimethylacethydrazine and N′,N″,N′″-trimethylacetimidohydrazine, respectively, to form as a first step, monomeric dimethylmetal derivatives with five-membered ring skeletons. These heterocyclic compounds immediately add a further alkylmetal molecule. The 1H NMR, IR and Raman spectra of these compounds are discussed and the results of X-ray structure determinations of two of the adducts are given. |
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