Evolution in shapes of a series of (111)-based In2O3 particles

In₂O₃ particles with different morphology were controllably synthesized on silicon substrates by thermal evaporation of In grains at 900 °C. The structure and morphology of the In₂O₃ particles were evaluated using X-ray diffraction, and scanning and transmission electron microscopies. The evolution in shapes as the ratio of {100} relative to {111} increases is clearly observed. The photoluminescence spectrum of the obtained In₂O₃ structures exhibits UV emission centered at about 378 nm and wide-band emission covering the green and orange regions with three peaks around 525, 572, and 604 nm. PACS 81.05.Hd; 81.07.Bc; 81.16.-c; 61.46.-w; 81.40.Gh