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Hydrocarboxylation of unactivated internal alkynes with carboxylic acids catalyzed by dinuclear palladium complexes
Authors:Naofumi Tsukada  Atsushi TakahashiYoshio Inoue
Affiliation:Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan
Abstract:
Dinuclear palladium complexes catalyzed addition reactions of carboxylic acid O-H bond to unactivated internal alkynes. The reaction afforded a trans-adduct selectively.
Keywords:Palladium   Catalysis   Carboxylic acid   Alkyne
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