| Hg(PMBP)2(HPMBP)2和Zn(PMBP)(H2O)Cl配合物的合成及结构 |
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| 引用本文： | 安兴民,贾殿赠,李勇. Hg(PMBP)2(HPMBP)2和Zn(PMBP)(H2O)Cl配合物的合成及结构[J]. 高等学校化学学报, 1987, 8(6): 485 |
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| 作者姓名： | 安兴民 贾殿赠 李勇 |
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| 作者单位： | 新疆大学化学系 |
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| 摘 要： | 用1-苯基-3-甲基-4-苯甲酰基吡唑啉酮-5(HPMBP)与HgCl2和ZnCl2·6H2O作用,分别合成化学式为[Hg(PMBP)2(HPMBP)2]和[Zn(PMBP)(H2O)Cl]的配合物;用元素分析、IR、1HNMR和电导等物理化学方法推测了配合物的分子结构式。配体在此螯合过程中皆由酮式转变为烯醇式,在Hg(Ⅱ)配合物中部分不变。
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| 收稿时间： | 1986-01-07 |
Synthesis of Hg(HPMBP),(PMBP)2and Zn(PMBP)(H2O)Cl Complexes and Their IR and 1H NMR |
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| An Xingmin,Jia Dianzheng,Li Yong. Synthesis of Hg(HPMBP),(PMBP)2and Zn(PMBP)(H2O)Cl Complexes and Their IR and 1H NMR[J]. Chemical Research In Chinese Universities, 1987, 8(6): 485 |
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| Authors: | An Xingmin Jia Dianzheng Li Yong |
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| Affiliation: | Department of Chemistry, Xingjiang University, Wulumuqi |
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| Abstract: | The coordination compounds of 1-phenyl-3-methyl-4-benzoylpyrazolone-5 (HPMBP) with Hg(Ⅱ) and Zn(Ⅱ) have been synthesised. The structures and properties of the compounds formed have been characterized by elemental analysis, IR, 1HNMR and Conductance measurements. The ligand used has been found to change from keto form to enolic form during the chelation reaction.The Hg(Ⅱ) is bohded by both the keto and enolic form producing a seldom 8-coordination compound. |
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