Early stages of ZnS nanoparticle growth studied by in-situ stopped-flow UV absorption spectroscopy. |
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Authors: | Michael Tiemann Ozlem Weiss Juha Hartikainen Frank Marlow Mika Lindén |
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Affiliation: | Institutionen f?r Fysikalisk Kemi, Abo Akademi, Porthansgatan 3-5, 20500 Abo, Finland. |
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Abstract: | The early stages of ZnS nanoparticle growth from supersaturated solution are investigated in situ by stopped-flow UV absorption spectroscopy with a time resolution of 1.28 ms. A model for data analysis is suggested which makes it possible to study both the average particle radius and the concentration. The average radii lie in the sub-nanometer range. During the first 40 ms, growth is predominantly governed by ripening. |
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Keywords: | absorption crystal growth nanostructures quantum dots UV/Vis spectroscopy |
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