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Highly Phosphorescent Crystals of Square‐Planar Platinum Complexes with Chiral Organometallic Linkers: Homochiral versus Heterochiral Arrangements,Induced Circular Dichroism,and TD‐DFT Calculations |
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| Authors: | Dr. Hugo Sesolis Dr. Julien Dubarle‐Offner Dr. Carmen K. M. Chan Emmanuel Puig Geoffrey Gontard Pierre Winter Prof. Andrew L. Cooksy Prof. Vivian W. W. Yam Dr. Hani Amouri |
| Affiliation: | 1. UPMC Paris 06, Institut Parisien de Chimie Moléculaire (IPCM) UMR CNRS 8232, Paris cedex 05, France;2. Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee, Hong Kong) and Department of Chemistry, The University of Hong Kong, Hong Kong, P. R. China;3. Department of Chemistry and Biochemistry, San Diego State University, San Diego, California, USA |
| Abstract: | A novel class of chiral luminescent square‐planar platinum complexes with a π‐bonded chiral thioquinonoid ligand is described. Remarkably the presence of this chiral organometallic ligand controls the aggregation of this square planar luminophor and imposes a homo‐ or hetero‐chiral arrangement at the supramolecular level, displaying non‐covalent Pt–Pt and π–π interactions. Interestingly these complexes are highly luminescent in the crystalline state and their photophysical properties can be traced to their aggregation in the solid state. A TD‐DFT calculation is obtained to rationalize this unique behavior. |
| Keywords: | molecular aggregation noncovalent interactions photophysical properties platinum supramolecular chirality |