Hydrogen‐bonding motifs in 4‐carboxyphenylammonium nitrate and perchlorate monohydrate,and in bis(4‐carboxyphenylammonium) sulfate |
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Authors: | S Athimoolam S Natarajan |
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Abstract: | In the title compounds, C7H8NO2+·NO3?, (I), C7H8NO2+·ClO4?·H2O, (II), and 2C7H8NO2+·SO42?, (III), the carboxyl planes of the 4‐carboxyphenylammonium cations are twisted from the aromatic plane. A homonuclear C(8) hydrogen‐bonding motif of 4‐carboxyphenylammonium cations is observed in both (I) and (II), leading to `head‐to‐tail' layers. The cations in (III) form carboxyl group dimers, making a graph‐set motif of R22(8). In all the structures, anions connect the cationic layers and an infinite chain running along the c axis is observed, having the C22(6) graph‐set motif. Interestingly, in (II), the anions are connected through weak hydrogen bonds involving the water molecules, leading to a graph‐set motif of R44(12). Alternate hydrophobic and hydrophilic layers are observed in all three compounds as a result of the column‐like arrangement of the aromatic rings of the cations and the anions. Furthermore, in (I), head‐to‐tail N—H?O interactions and interactions linking the cations and anions form an R64(16) hydrogen‐bonding motif, resulting in a pseudo‐inversion centre at (, , 0). |
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