Abstract: | The title compound anilinium chloride–4‐bromo‐N‐phenylbenzenesulfonamide (1/1), C6H8N+·Cl?·C12H10BrNO2S, displays a hydrogen‐bonded ladder motif with four independent N—H?Cl bonds in which both the NH group of the sulfonamide molecule and the NH3 group of the anilinium ion N?Cl = 3.135 (3)–3.196 (2) Å and N—H?Cl = 151–167°] are involved. This hydrogen‐bonded chain contains two independent R42(8) rings and each chloride ion acts as an acceptor of four hydrogen bonds. |