Dichloro[(1E,1′E)‐1,1′‐(pyridine‐2,6‐diyl)diethanone bis(O‐methyloxime)‐κ3N1,N2,N6]copper(II) |
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Authors: | Osman Dayan Muharrem Diner Bekir etinkaya Namk
zdemir |
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Abstract: | In the title compound, CuCl2(C11H15N3O2)], the CuII ion is five‐coordinated in a strongly distorted trigonal–bipyramidal arrangement, with the two methyloxime N atoms located in the apical positions, and the pyridine N and the Cl atoms located in the basal plane. The two axial Cu—N distances are almost equal (mean 2.098 Å) and are substantially longer than the equatorial Cu—N bond 1.9757 (15) Å]. It is observed that the N(oxime)—M—N(pyridine) bond angle for five‐membered chelate rings of 2,6‐diacetylpyridine dioxime complexes is inversely related to the magnitude of the M—N(pyridine) bond. The structure is stabilized by intra‐ and intermolecular C—H?Cl hydrogen bonds which involve the methyl H atoms, except for one of the two acetylmethyl groups. |
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