Abstract: | In the title compound, 2‐hydroxy‐1,2‐diphenylethanone 4‐ethylthiosemicarbazone, C17H19N3OS, the thiosemicarbazone moiety is planar and has an E configuration. The planar phenyl rings make dihedral angles of 82.34 (8) and 8.07 (17)° with the plane of the thiosemicarbazone moiety. The crystal structure contains two intramolecular (N—H?O and N—H?N) and one intermolecular interaction (O—H?S), as well as two C—H?π(benzene) interactions. Molecules are stacked in columns running along the a axis. Molecules in each column are connected to each other by means of linear O—H?S hydrogen bonds and C—H?π interactions. In addition, there are also C—H?π(benzene) interactions between the columns. |