Poly[[[bis(N,N′‐dimethylformamide)zinc(II)]‐μ3‐5‐hydroxybenzene‐1,3‐dicarboxylato] toluene solvate] |
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Authors: | Young Ho Jhon Jaheon Kim |
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Abstract: | The title compound, {Zn(C8H4O5)(C3H7NO)2]·0.5C7H8}n, is a one‐dimensional coordination polymer in which the Zn atoms are linked by bridging 5‐hydroxybenzene‐1,3‐dicarboxylate ligands. These polymeric chains form two‐dimensional sheets via interchain hydrogen bonds, and these sheets, in turn, are stacked tightly with solvent toluene molecules in the interlayer space. The N,N′‐dimethylformamide ligands, coordinated axially to the Zn atoms, form van der Waals contacts with ligands in neighboring sheets, and enclose the guest molecules. |
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