Bis(acesulfamato‐κ2O4,N)bis(3‐methylpyridine)copper(II) |
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Authors: | Necmi Dege Hasan Ibudak Elif Adyaman |
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Abstract: | In the crystal structure of the title compound {systematic name: bis6‐methyl‐1,2,3‐oxathiazin‐4(3H)‐one 2,2‐dioxide(1?)‐κ2N3,O4]bis(3‐methylpyridine)copper(II)}, Cu(C4H4NO4S)2(C6H7N)2], the CuII centre resides on a centre of symmetry and has an octahedral geometry that is distorted both by the presence of four‐membered chelate rings and because of the Jahn–Teller effect. The equatorial plane is formed by the N atoms of two methylpyridine ligands and by the more basic O atoms of the acesulfamate ligands, while the weakly basic N atoms of these ligands are in elongated axial positions with a misdirected valence. The crystal is stabilized by two intermolecular C—H?O interactions involving the methyl and CH groups, and the sulfonyl O atoms of the acesulfamate group. |
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