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Poly[[μ‐aqua‐bis­(μ‐2,4‐dichloro­phen­oxy­acetato)barium(II)] monohydrate]
Authors:Chang‐Sheng Gu  Xiao‐Min Hao  Shu‐Xia Guan  Ji‐Wei Liu
Abstract:In the title coordination polymer, {Ba(C8H5Cl2O3)2(H2O)]·H2O}n, each BaII atom is nine‐coordinated by six carboxyl­ate O atoms and one ether O atom from five symmetry‐related 2,4‐dichloro­phenoxy­acetate ligands, and by two O atoms from water mol­ecules, thus defining a distorted tricapped trigonal prism. The BaII ions are bridged by bidentate water mol­ecules and by tridentate and tetra­dentate 2,4‐dichloro­phenoxy­acetate groups, leading to a two‐dimensional layer structure. The crystal structure is further stabilized by hydrogen‐bonding inter­actions within each layer.
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