Poly[[μ‐aqua‐bis(μ‐2,4‐dichlorophenoxyacetato)barium(II)] monohydrate] |
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Authors: | Chang‐Sheng Gu Xiao‐Min Hao Shu‐Xia Guan Ji‐Wei Liu |
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Abstract: | In the title coordination polymer, {Ba(C8H5Cl2O3)2(H2O)]·H2O}n, each BaII atom is nine‐coordinated by six carboxylate O atoms and one ether O atom from five symmetry‐related 2,4‐dichlorophenoxyacetate ligands, and by two O atoms from water molecules, thus defining a distorted tricapped trigonal prism. The BaII ions are bridged by bidentate water molecules and by tridentate and tetradentate 2,4‐dichlorophenoxyacetate groups, leading to a two‐dimensional layer structure. The crystal structure is further stabilized by hydrogen‐bonding interactions within each layer. |
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