(4‐Bromo‐2‐formylphenolato)perchlorato(1,10‐phenanthroline)copper(II) |
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Authors: | Hong‐Yan Wu Yun‐Feng Feng Shu‐Rong Wang Wei‐Ping Huang |
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Abstract: | In the title copper(II) compound, Cu(C7H4BrO2)(ClO4)(C12H8N2)], the Cu atom is five‐coordinated in a distorted square‐pyramidal geometry by the N‐ and O‐donors of 4‐bromo‐2‐formylphenolate, 1,10‐phenanthroline and perchlorate. Pairs of complexes are linked together by Cu⋯O(phenolate) and π–π stacking interactions between 4‐bromo‐2‐formylphenolate and 1,10‐phenanthroline. Along the crystallographic a axis, the dimers are linked by hydrogen bonds between a perchlorate O atom and a 4‐bromo‐2‐formylphenolate H atom, and by further π–π stacking interactions. Hydrogen bonding between the Br atom and a 1,10‐phenanthroline H atom takes place between the stacks of dimers. |
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