Abstract: | The structures of three chiral vinyldioxazaborocanes are reported, namely (2E)‐ and (2Z)‐6‐benzyl‐2‐buten‐2‐yl‐1,3,6,2‐dioxazaborocane, C27H30BNO2, (II) and (III), respectively, and (2Z)‐2‐buten‐2‐yl‐6‐isobutyl‐1,3,6,2‐dioxazaborocane, C24H32BNO2, (IV). These compounds may be useful in asymmetric reactions. In the structures reported here, the N—B donor–acceptor bond is longer than in any previously reported analogous compounds. |