|
|||||
|
|
An ionic 2D inorganic–organic hybrid of tris[((1H-tetrazol-5-yl)methyl) morpholine] dodecatungstophosphate(V) pentahydrate: Synthesis X-ray crystal structure, and spectroscopic characterizations |
|
| Authors: | Mohsen Nikpour Hossein Eshtiagh-Hosseini Masoud Mirzaei Amir Aghaei Kaju Ya Guang Chen Soroush Zarinabadi |
| Institution: | Department of Chemistry, School of Sciences, Islamic Azad University, Ahvaz Branch, Ahvaz, 61349—68875, Iran Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P.O. Box 917791436, Iran Department of Chemistry, Khorassan Science & Technology Park, Mashhad, P.O. Box 91735139, Iran Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, China |
| Abstract: | A unique ionic hybrid material C6H12N5O]3(PO4)W12O36]•5H2O has been synthesized from the reaction of ((1H-tetrazole-5-yl)methyl)morpholine and α-H3(PO4)W12O36].21H2O. It has successfully been characterized by elemental analysis, IR and 1H NMR spectroscopies, TGA and single-crystal X-ray diffraction method. The title compound is constructed from the three C6H12N5O]+ cations and α-Keggin (PO4)W12O36]3- polyoxoanion. The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like (2D/∞(PO4)W12O36]3-) which forming via van der Waals interactions along the x axis. |
| Keywords: | Polyoxometalate Inorganic-organic hybrid Morpholine Dodecatungstophosphate Crystal structure |
| 点击此处可从《中国化学快报》浏览原始摘要信息 | |
| 点击此处可从《中国化学快报》下载免费的PDF全文 | |