| 一种含二茂铁基的多枝状分子的合成、表征及其性质研究 |
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| 引用本文： | 左从玉,周永红,吴杰颖,田玉鹏.一种含二茂铁基的多枝状分子的合成、表征及其性质研究[J].无机化学学报,2004,20(9):1018-1022. |
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| 作者姓名： | 左从玉 周永红 吴杰颖 田玉鹏 |
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| 作者单位： | 1. 安徽大学化学化工学院,合肥,230039
2. 安徽大学化学化工学院,合肥,230039;南京大学配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.50272001，20071001)，安徽省自然科学基金资助项目(No.03044701)。 |
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| 摘 要： | 采用新的方法合成了一种二茂铁衍生物——均三（二茂铁乙烯基）苯，通过元素分析、红外光谱、核磁共振氢谱、质谱、紫外可见光谱等对其进行了表征。用循环伏安法对其电化学性质进行了初步研究，用Z-扫描技术测试了它的非线性光学性能。结果表明，该化合物具有良好的电化学及非线性光学性质。
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| 关 键 词： | 二茂铁衍生物 Wittig反应 循环伏安法 电化学 Z-扫描 双光子吸收 |
| 修稿时间： | 2004年3月2日 |
Synthesis, Characterization and Electrochemical and Nonlinear Optical Properties of a Dendritic Molecule Containing Ferrocene Units |
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| ZUO Cong-Yu,ZHOU Yong-Hong,WU Jie-Ying and TIAN Yu-Peng.Synthesis, Characterization and Electrochemical and Nonlinear Optical Properties of a Dendritic Molecule Containing Ferrocene Units[J].Chinese Journal of Inorganic Chemistry,2004,20(9):1018-1022. |
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| Authors: | ZUO Cong-Yu ZHOU Yong-Hong WU Jie-Ying and TIAN Yu-Peng |
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| Institution: | School of Chemistry & Engineering, Anhui University, Hefei 230039,School of Chemistry & Engineering, Anhui University, Hefei 230039,School of Chemistry & Engineering, Anhui University, Hefei 230039 and School of Chemistry & Engineering, Anhui University, Hefei 230039;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | A new synthetic method is designed for a ferrocenyl derivative, 1,3,5-tris(ferrocenylethenyl)benzene, which has been characterized by elemental analysis, IR, 1H NMR and MS. Furthermore, its electrochemical properties have been investigated using cyclic voltammetry method. The two-photon absorption of the compound was measured using the Z-scan technique at 532 nm. The results indicate that the compound has good electrochemical properties and strong NLO effects. |
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| Keywords: | ferrocene derivative Wittig reaction cyclic voltammetry electrochemistry Z-scan method two-photon absorption (TPA) |
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