Steady-State Spectroscopic and Fluorescence Lifetime Measurements of New Two-Photon Absorbing Fluorene Derivatives

Steady-state excitation anisotropy, lifetimes, and time-resolved emission spectra of new 2-photon absorbing fluorene derivatives were measured in aprotic solvents at room temperature. Excitation anisotropy spectra in viscous silicon oil allowed the determination of the spectral position of three electronic transitions S₀ S₁, S₀ S₂, S₀ S₃ (S_i, i = 1, 2, 3 are the singlet electronic states) and the angles ( 30°) between absorption S₀ S₁ and emission S₁ S₀ dipole moments for the first electronic transition. Solvate relaxation processes in the first excited state of the investigated fluorene molecules affect the lifetimes of these states, ₁, so that experimental values of ₁ do not correspond to those calculated by Strickler and Berg theory. The influence of the molecular concentration on the fluorescence quantum yields and ₁ have been investigated.