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Turn-on fluorescence sensing of cyanide ions in aqueous solution
基金项目:This work was supported by the National Natural Science Foundation of China (Nos. 21064006, 21262032 and 21161018), the Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (No. IRT1177), the Natural Science Foundation of Gansu Province (No. 1010RJZA018), the Youth Foundation of Gansu Province (No. 2011GS04735) and NWNU-LKQN-11-32.
摘    要:
A sensitive fluorescent probe, 2,2'-bisbenzimidazole (L), for CN has been developed. This structurally simple receptor displays great selectivity for the cyanide anion over other common inorganic anions in an aqueous environment. In addition, further study demonstrates the lower detection of the fluorescence response of the sensor to CN is in 10 9 mol/L range. Thus, the present probe should be applicable as a practical system for the monitoring of cyanide concentrations in aqueous samples.

关 键 词:水溶液  光传感  氰离子  无机阴离子  检测传感器  荧光探针  苯并咪唑  荧光反应
收稿时间:2013-07-14
修稿时间:2013-09-18

Turn-on fluorescence sensing of cyanide ions in aqueous solution
Jun Liu,Qi Lin,Hong Yao,Miao Wang,You-Ming Zhang,Tai-Bao Wei. Turn-on fluorescence sensing of cyanide ions in aqueous solution[J]. Chinese Chemical Letters, 2014, 25(1): 35-38. DOI: 10.1016/j.cclet.2013.10.026
Authors:Jun Liu  Qi Lin  Hong Yao  Miao Wang  You-Ming Zhang  Tai-Bao Wei
Affiliation:Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
Abstract:
A sensitive fluorescent probe, 2,2'-bisbenzimidazole (L), for CN- has been developed. This structurally simple receptor displays great selectivity for the cyanide anion over other common inorganic anions in an aqueous environment. In addition, further study demonstrates the lower detection of the fluorescence response of the sensor to CN- is in 10-9 mol/L range. Thus, the present probe should be applicable as a practical system for the monitoring of cyanide concentrations in aqueous samples.
Keywords:Fluorescent probe  2,2&rsquo  -Bisbenzimidazole  Cyanide  Aqueous solution
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