Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of a New Dinuclear Copper Complex [C2H6ON]2[Cu2Cl2(μ-CH3COO)4] |
| |
引用本文: | 许瑞波,许兴友,王明艳,杨绪杰,汪信,陆路德,马卫兴.Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of a New Dinuclear Copper Complex [C2H6ON]2[Cu2Cl2(μ-CH3COO)4][J].结构化学,2009(6):703-707. |
| |
作者姓名: | 许瑞波 许兴友 王明艳 杨绪杰 汪信 陆路德 马卫兴 |
| |
作者单位: | Materials;Chemistry;Laboratory;Nanjing;University;Science;Technology;Department;Chemical;Engineering;Huaihai;Institute; |
| |
基金项目: | Supported by the High Technical Foundation of Jiangsu Province (BG2007047);;the Key Project for Fundamental Research and Natural Science Foundation of Jiangsu Provincial Educational Commission (07KJA150011 and 05KJB150003) |
| |
摘 要: | The hydrothermal reaction of copper chloride dihydrate and 5,5-dimethyl-imidazolidine,-2,4-dione with a mole ratio of 1:1 in acetonitrile resulted in the formation of a new acetate-bridged dinuclear copper complex, C2H6ON]2Cu2Cl2(μ-CH3COO)4]. Protonated acetamide in eaolie form and acetic acid were yielded by the hydrolysis of acetonitrile under hydrothennal condition. The rifle complex (C12H24Cl2Cu2N2O10) was characterized by X-ray single-crystal diffraction, IR spectrum, elemental and electrochemical analysis. It crystallizes in the monoclinic system, space group P21/c with a = 8.298004), b = 14.358(2), c = 12.0010(2) A^°, β= 130.620(3)°, V = 1085.3(2) A^°^3, Dc = 1.696 g/cm^3, 34, = 554.31, Z = 2, F(000) = 564 and μ = 2.254 mm^-1. The crystal structure consists of a tetraacetate-bridging dinulcear copper complex anion Cu2Cl2(μ-CH3COO)4]^2-, with the chlorine anions in the axial positions, and two protonated acetamide cations C2H6ON]^+, which were connected through hydrogen bonds to form a three-dimensional infinite network.
|
关 键 词: | 双核铜配合物 水热合成 晶体结构 电化学性能 醋酸 电化学分析 水热反应 单晶衍射 |
本文献已被 CNKI 维普 等数据库收录! |
|