Epoxidation Functionalized Isobutylene Isoprene Rubber toward Green-curing Pathway and High-performance Composites |
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作者姓名: | Han Gao Bai-Chuan Cui Hong-Bing Zheng Fu-Lan Hao Yan Shi Li-Qun Zhang |
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作者单位: | 1. Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology |
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基金项目: | financially supported by the National Key Research and Development Program of China;;the National Natural Science Foundation of China (Nos. 2022YFB3704800, 2022YFB3704802 and 52273051);;the Fundamental Research Funds for the Central Universities (No. JD2221); |
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摘 要: | Epoxidation of the carbon-carbon double bonds on unsaturated rubber macromolecules can produce novel modified rubber species with special properties, and construct eco-friendly crosslinking pathway via the reaction of epoxide groups to solve the problems brought by conventional sulfur vulcanization system. In this contribution, a novel modified product of isobutylene isoprene rubber(IIR), epoxyfunctionalized IIR(EIIR) was successfully prepared by in situ epoxidation technique for the first time,...
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