New access to H-phosphonates via metal-catalyzed phosphorus-oxygen bond formation |
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| Authors: | Coudray Laëtitia Abrunhosa-Thomas Isabelle Montchamp Jean-Luc |
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| Affiliation: | Department of Chemistry, Texas Christian University, Box 298860, Fort Worth, TX 76129, USA |
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| Abstract: | A novel approach to H-phosphonates from hypophosphorous acid using a transfer hydrogenation process was developed. This method is atom-economical, environmentally friendly, catalytic, and efficient, leading easily to H-phosphonate monoesters or ammonium salt in moderate to good yields. |
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