Revisit to the reaction of [60]fullerene with nitrile ylides generated from imidoyl chlorides and triethylamine |
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| Authors: | Guan-Wu Wang Hai-Tao Yang |
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| Institution: | Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China |
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| Abstract: | The reaction of 60]fullerene (C60) with nitrile ylides generated from N-benzyl-4-nitrobenzimidoyl chloride/N-(4-chlorobenzyl)-4-nitrobenzimidoyl chloride and triethylamine gave only isomeric monoadducts of C60 with 6,6]-closed structure. No 5,6]-open adduct of C60 could be identified from these reactions. The previously reported 5,6]-open product of C60 should be reassigned as a 6,6]-closed product. |
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| Keywords: | [60]Fullerene Nitrile ylide Imidoyl chloride 1 3-Dipolar reaction Cycloaddition |
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