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Novel biomimetic iron-catalysts for environmentally benign epoxidations of olefins |
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| Authors: | Kristin Schrö der,Bianca Bitterlich,Feyissa Gadissa Gelalcha,Matthias Beller |
| Affiliation: | a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, D-18059 Rostock, Germany b University of Rostock, Center for Life Science Automation (CELISCA), Friedrich-Barnewitz-Strasse 8, D-18119 Rostock, Germany c Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Richard-Willstätter-Strasse 12, D-12489 Berlin, Germany |
| Abstract: | A new selective and easily manageable epoxidation method is presented using an inexpensive and efficient FeCl3·6H2O and imidazole derivatives as catalysts. Aqueous hydrogen peroxide as an environmentally benign oxidant is utilized. This novel Fe/imidazole system gives moderate to excellent yields toward aromatic mono-, di-, and tri-substituted olefins. |
| Keywords: | Iron Epoxidation Imidazole Hydrogen peroxide |
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