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Enantioselective synthesis of (R)-deoxydysibetaine and (−)-4-epi-dysibetaine |
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| Authors: | Miho Katoh |
| Affiliation: | Faculty of Pharmaceutical Sciences, Hoshi University, Ebara 2-4-41, Shinagawa-ku, Tokyo 142-8501, Japan |
| Abstract: | Enantioselective synthesis of (R)-deoxydysibetaine and (−)-4-epi-dysibetaine was achieved by employing a samarium iodide-promoted reductive carbon-nitrogen bond cleavage of a proline derivative, as a key reaction. |
| Keywords: | (R)-Deoxydydibetaine (&minus )-4-epi-Dysibetaine Samarium iodide Reductive carbon-nitrogen bond cleavage α,α-Disubstituted amino acid |
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