Radical trifluoromethylation of ammonium enolates |
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| Authors: | Vitaliy Petrik |
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| Affiliation: | UMR 6014 CNRS de l’IRCOF, Université et INSA de Rouen, F-76821 Mont-Saint-Aignan Cedex, France |
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| Abstract: | The easy radical trifluoromethylation of a series of 1,3-dicarbonyl compounds with CF3I is described. The reaction occurs in the presence of a nitrogen base and sodium dithionite in CH3CN-H2O solution. Additionally, we report a new access to ammonium triflinates. |
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| Keywords: | Fluorine compounds Trifluoromethylation Radical reaction 1,3-Dicarbonyl compounds Triflinates |
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