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Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions
Authors:Seo Mi Sook  Kamachi Takashi  Kouno Tomohisa  Murata Koji  Park Mi Joo  Yoshizawa Kazunari  Nam Wonwoo
Institution:Department of Chemistry, Division of Nano Sciences and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea. kazunari@ms.ifoc.kyushu-u.ac.jp
Abstract:
Keywords:density functional calculations  enzyme models  iron  oxo ligands  oxygenation
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