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Synthesis and Luminescence Characteristics of LiMgAlF6:Ln3+ (Ln = Ce,Eu, Tb)
Authors:Feng Tao  Xiao-Jing Zhou  Shi-Fu Zhu  Bei-Jun Zhao  Guang-Yan Hong  Hong-Peng You
Abstract:By solid state reaction, LiMgAlF6 and LiMgAlF6: Ln3+ are synthetized with the ratio 120/100/110 of LiF/MgF2/AlF3, at 1008 K, in high-purity Ar stream. Their crystal structure which belongs to hexagonal system are determined by X-Ray-Diffraction (XRD). Luminescence characteristics of Ce3+, Eu3+, Tb3+ and sensitization of Ce3+ to Tb3+ in LiMgAlF6 are studied. It is shown that the sensitization of Ce3+ to Tb3+ is efficient and a bright green emission is observed.
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