The d2/d3 alkyne redox pair [WF2(PhC identical to CPh)Tp']z (z = +1 or 0): missing links in a 'redox family tree' |
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| Authors: | Adams Christopher J Anderson Kirsty M Connelly Neil G Harding David J Orpen A Guy Patron Elena Rieger Philip H |
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| Institution: | School of Chemistry, University of Bristol, Bristol, UK BS8 1TS. |
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| Abstract: | The d2/d3 redox pair WF2(PhC identical to CPh)Tp']z z = +1 or 0, Tp' = hydrotris(3,5-dimethylpyrazolyl)borate] is the missing link in a 'redox family tree' relating the d6 tricarbonyls M(CO)3L]- to the d2 trihalides MX3L] (M = Mo or W, L = Cp or Tp') by a series of stepwise reactions involving sequential one-electron oxidation followed by ligand substitution. |
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