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Selective oxidation of cyclooctane to cyclootanone with molecular oxygen in the presence of compressed carbon dioxide
Authors:Theyssen Nils  Leitner Walter
Institution:Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1 45470, Mülheim an der Ruhr, Germany.
Abstract:The oxidation of cyclooctane (1) to cyclooctanone (3) with molecular oxygen and acetaldehyde (2) as a co-reductant occurs efficiently in the presence of compressed CO2. Up to 20% yields of 3 are obtained under optimised multiphase conditions.
Keywords:
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