Reductive complexation of cycloheptatrienes by iron pentacarbonyl and catalytic sodium borohydride |
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Authors: | Coquerel Yoann Deprés Jean-Pierre |
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Institution: | LEDSS, Université Joseph Fourier, Batiment Chimie Recherche, 301 rue de la Chimie, BP 53, 38041 Grenoble, France. |
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Abstract: | Fe(CO)5 and a catalytic amount of sodium borohydride react with cycloheptatrienes in protic solvents to yield the corresponding tricarbonyl(eta 4-1,3-diene)iron complexes in a one-pot procedure, which has been found to be particularly efficient for the synthesis of the useful tricarbonyl(cyclo-heptadiene)iron complex. |
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