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Change of the scaling behavior of the end-to-end square distance in a two-dimensional polydisperse system
Authors:Y. Rouault
Affiliation:(1) Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, DE
Abstract:
The simulation of a two-dimensional, broadly polydisperse, living polymers system at high concentration reveals an unusual conformational behaviour for the longer chains. Unlike in three dimensions, the longer chains are not swollen but are squeezed by the smaller chains. This observation is discussed in terms of a two dimensional solvent- polymer mixture whose solvent particules are larger than the polymer monomers. Received: 13 December 1996 / Revised: 16 March 1998 / Accepted: 27 March 1998
Keywords:PACS. 61.25.Hq Macromolecular and polymer solutions   polymer melts   swelling - 05.50.+q Lattice theory and statistics   Ising problems - 64.60.Cn Order-disorder transformations   statistical mechanics of model systems
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