Chlorination of V2O5 by CCl4. The proposed reaction mechanism |
| |
| Authors: | G Mink I Bertóti C Battistoni and T Székely |
| |
| Institution: | (1) Research Laboratory for Inorganic Chemistry of the Hungarian Academy of Sciences, Pf. 132, H-1502 Budapest, Hungary;(2) Istituto di Teoria e Struttura Elettronica, CNR, Roma, Italy |
| |
| Abstract: | Initial stage of the reaction of CCl4 with V2O5 has been studied by MS and XPS techniques. According to the proposed mechanism dissociatively chemisorbed CCl4 transforms to CO2 via adsorbed COCl2, while surface vanadium atoms involved are gaining step by step two chlorine atoms before the formation of the volatile end-product VOCl3.
                 CCl4 V2O5             .   - CCl4 CO2 COCl2, VOCl3.
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
