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Acid-induced rearrangement of cycloadducts from N-aryl itaconimides and 1,3-diphenylisobenzofuran |
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| Authors: | Alexander V. Stepakov Vitaly M. Boitsov Anna G. Larina Alexander P. Molchanov |
| Affiliation: | 1. Chemistry Department, Saint-Petersburg State University, Universitetsky prosp. 26, St-Petersburg 198504, Russian Federation;2. Saint-Petersburg Academic University—Nanotechnology Research and Education Centre RAS, Khlopin Str. 8/3, St-Petersburg 194021, Russian Federation |
| Abstract: | Treatment of several Diels–Alder adducts of N-aryl itaconimides and 1,3-diphenylisobenzofuran with a strong acid triggers a skeletal rearrangement resulting in 2-aryl-6,10b-diphenylbenzo[h]isoquinoline-1,3(2H,10bH)-diones. |
| Keywords: | VKIKFTQLOAYGIM-UHFFFAOYSA-N QMALJNNXMWNPLF-UHFFFAOYSA-N QGRKEVUAUDZYPX-UHFFFAOYSA-N MZELESZGIDPYTI-UHFFFAOYSA-N BNIDIWPAACDIHJ-UHFFFAOYSA-N IDIGTPIWURYPIL-UHFFFAOYSA-N MBCCKXSKJCHSMN-UHFFFAOYSA-N IASRIYYMDZFQAT-UHFFFAOYSA-N |
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