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Simple method for selective oxidation of 1,2-diols in water with KBrO3/KHSO4
Authors:Julius M. William  Masami KuriyamaOsamu Onomura
Affiliation:Graduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan
Abstract:
Readily available off-the-shelf KBrO3 and KHSO4 have been used to selectively oxidize 1,2-diols in water as a solvent. Various cyclic 1,2-diols have been tolerated affording their corresponding α-hydroxy ketones in good yields.
Keywords:Water   Oxidation   1,2-Diol   α-Hydroxy ketone
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